Caitllyn has advantages of range better than xayah because of her passive combine with her skill, try to reduce her range or add multiple CC effects if your team have the catching supporters or combat open champions (Rakan, Nocturne, Hecarim, Leona, Pyke, Galio, ...).
Tristana
Tristana will be the high threat if she has the best synergy support champions, try not to engage her quickly if you don't have sufficient distance with her jumping W.
Kalista
Kalista can dodge the feathers zone while hit and runs because of the attack speed more than you in late game. Try to keep her at bay before engaging her
Leona
Xayah will be vulnerable when hitting Leona's ultimate or E + flash, Consider going cleanse, anti CC items
Akali
Akali has the 3 dashes, smoke bomb to finish you quickly, so try to keep distance with her asap, lure her out of the smoke zone.
Talon
Talon can finish you quickly when he has ultimate ability, so try not to engage him at the close distance or the circle blade zone R.
Pyke
The hardest matchup for Xayah is a botlane with Pyke support. Pyke can get you out of position and keep you there with chain CC. I find it best to just play under tower or behind multple creeps when laning against Pyke.
Mordekaiser
Mordekaiser can finish you quickly when stucking inside his r ability, if the zone has the hard terrain, his ability is not the big deal enough, otherwise, consider going cleanse and anti cc items
Master Yi
Yi can make the closest distance with q and r, try to keep long distance if he is under team controls.
Annie
Annie can make the stun combo with R and full passive stacks, Consider going cleanse, anti CC items
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